dc.contributor.author
Saladrigas, Mar
dc.contributor.author
Bonjoch i Sesé, Josep
dc.contributor.author
Bradshaw, Ben
dc.date.issued
2020-05-12T16:03:41Z
dc.date.issued
2020-12-30T06:10:20Z
dc.date.issued
2019-12-30
dc.date.issued
2020-05-12T16:03:41Z
dc.identifier
https://hdl.handle.net/2445/159735
dc.description.abstract
Iron-catalyzed hydrogen atom transfer-mediated intermolecular C−C coupling reactions between alkenes and tosylhydrazones, followed by in situ cleavage of the tosylhydrazine intermediates using Et3N, are described. The process involves a new strategic bond disconnection resulting in the reductive alkylation of nonactivated alkenes. The reaction is operationally simple, proceeds under mild conditions, and has a wide substrate scope.
dc.format
application/pdf
dc.publisher
American Chemical Society
dc.relation
Versió postprint del document publicat a: https://doi.org/10.1021/acs.orglett.9b04459
dc.relation
Organic Letters, 2019, vol. 22, num. 2, p. 684-688
dc.relation
https://doi.org/10.1021/acs.orglett.9b04459
dc.rights
(c) American Chemical Society , 2019
dc.rights
info:eu-repo/semantics/openAccess
dc.source
Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica)
dc.title
Iron hydride radical reductive alkylation of unactivated alkenes
dc.type
info:eu-repo/semantics/article
dc.type
info:eu-repo/semantics/acceptedVersion