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Synthesis of cis-hydrindan-2,4-diones bearing an all.carbon quaternary center by a Danheiser annulation

Author

Saborit Villarroya, Gisela

Cativiela, Carlos

Jimenez, Ana I.

Bonjoch i Sesé, Josep

Bradshaw, Ben

Publication date

2019-02-13T12:54:14Z

2019-02-13T12:54:14Z

2018-10-09

2019-02-13T12:54:14Z

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Abstract

A straightforward synthetic entry to functionalized hydrindane compounds based on a rapid assembly of the core nucleus by a Danheiser cycloaddition is reported. Valuable bicyclic building blocks containing the fused five and six-membered carbocyclic ring system can be achieved in only four steps from a simple acyclic β-keto ester. Keywords: alkaloid; Danheiser annulation; decahydroquinoline

Document Type

Article

Published version

Language

English

Subjects and keywords

Ciclització (Química); Alcaloides; Síntesi orgànica; Ring formation (Chemistry); Alkaloids; Organic synthesis

Publisher

Beilstein Institute

Related items

Reproducció del document publicat a: https://doi.org/10.3762/bjoc.14.237

Beilstein Journal of Organic Chemistry, 2018, vol. 14, p. 2597-2601

https://doi.org/10.3762/bjoc.14.237

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DIDL MARC MARC_CCUC METS OAI_DC ORE QDC RDF

Rights

cc-by (c) Saborit Villarroya, Gisela et al., 2018

http://creativecommons.org/licenses/by/3.0/es

This item appears in the following Collection(s)

Farmacologia, Toxicologia i Química Terapèutica [675]

ISGlobal - Institut de Salut Global de Barcelona [60793]