2018-03-08T14:19:19Z
2018-03-08T14:19:19Z
2014-01-06
2018-03-08T14:19:19Z
The interaction of imines with isocyanides has been studied. The main product results from a sequential process involving the attack of two units of isocyanide, under Lewis acid catalysis, upon the carbon-nitrogen double bond of the imine to form the 4-membered ring system. The scope of the reaction regarding the imine and isocyanide ranges has been determined, and also some mechanistic variations and structural features have been described.
Artículo
Versión publicada
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Isonitrils; Imines; Compostos heterocíclics; Reaccions químiques; Química orgànica; Isocyanides; Imines; Heterocyclic compounds; Chemical reactions; Organic chemistry
Beilstein Institute
Reproducció del document publicat a: https://doi.org/10.3762/bjoc.10.3
Beilstein Journal of Organic Chemistry, 2014, vol. 10, p. 12-17
https://doi.org/10.3762/bjoc.10.3
cc-by (c) Ghashghaei, Ouldouz et al., 2014
http://creativecommons.org/licenses/by/3.0/es