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Synthesis, properties and applications of biodegradable polymers derived from diols and dicarboxylic acids: from polyesters to poly(ester amide)s
Díaz Andrade, Angélica María; Katsarava, Ramaz; Puiggalí Bellalta, Jordi
Universitat Politècnica de Catalunya. Departament d'Enginyeria Química; Universitat Politècnica de Catalunya. PSEP - Polimers Sintètics: Estructura i Propietats. Polimers Biodegradables.
Poly(alkylene dicarboxylate)s constitute a family of biodegradable polymers with increasing interest for both commodity and speciality applications. Most of these polymers can be prepared from biobased diols and dicarboxylic acids such as 1,4-butanediol, succinic acid and carbohydrates. This review provides a current status report concerning synthesis, biodegradation and applications of a series of polymers that cover a wide range of properties, namely, materials from elastomeric to rigid characteristics that are suitable for applications such as hydrogels, soft tissue engineering, drug delivery systems and liquid crystals. Finally, the incorporation of aromatic units and alpha-amino acids is considered since stiffness of molecular chains and intermolecular interactions can be drastically changed. In fact, poly(ester amide)s derived from naturally occurring amino acids offer great possibilities as biodegradable materials for biomedical applications which are also extensively discussed.
Àrees temàtiques de la UPC::Enginyeria química
Polymers--Biodegradation
poly(alkylene dicarboxylate)s
poly(ester amide)s
alpha-amino acid derivatives
bio-based polymers
carbohydrate derivatives
biodegradability
scaffolds
biomedical applications
ALIPHATIC-AROMATIC COPOLYESTERS
LIPASE-CATALYZED SYNTHESIS
ALPHA-AMINO-ACIDS
NATURALLY-OCCURRING MONOSACCHARIDES
BUTYLENE SUCCINATE) COPOLYMERS
THERMAL-DEGRADATION MECHANISM
STEP-GROWTH POLYMERIZATION
CO-PROPYLENE SUCCINATE)S
POLY(ETHER ESTER AMIDE)S
SOLID-STATE MODIFICATION
Polímers -- Biodegradació
Attribution-NonCommercial-NoDerivs 3.0 Spain
http://creativecommons.org/licenses/by-nc-nd/3.0/es/
info:eu-repo/semantics/publishedVersion
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