1. Home
  2. Universitat de Barcelona
  3. Institut de Nanociència i Nanotecnologia (IN2UB)
  4. View Item

A ferric guest inside a spin crossover ferrous helicate

Author

Barrios Moreno, Leoní Alejandra

Diego, Rosa

Darawsheh, Mohanad D.

Martínez, Jesús I.

Roubeau, Olivier

Aromí Bedmar, Guillem

Publication date

2023-03-21T18:44:50Z

2023-04-05T05:10:27Z

2022-04-05

2023-03-21T18:44:50Z

Share

Abstract

A designed dimetallic Fe(II) helicate made with biphenylenebridged bispyrazolylpyridine ligands and exhibiting a process of spin crossover at temperatures above ambient is shown to encapsulate an S = 5/2 tris-oxalato Fe(III) ion. The spin relaxation dynamics of this guest are strongly reduced upon encapsulation

Document Type

Article

Accepted version

Language

English

Subjects and keywords

Lligands; Ferro; Química supramolecular; Ligands; Iron; Supramolecular chemistry

Publisher

Royal Society of Chemistry

Related items

Versió postprint del document publicat a: https://doi.org/10.1039/d2cc00928e

Chemical Communications, 2022, vol. 58, num. 35, p. 5375-5378

https://doi.org/10.1039/d2cc00928e

Recommended citation

This citation was generated automatically.

Export

DIDL MARC MARC_CCUC METS OAI_DC ORE QDC RDF

Rights

(c) Barrios Moreno, Leoní Alejandra et al., 2022

This item appears in the following Collection(s)

Institut de Nanociència i Nanotecnologia (IN2UB) [375]

ISGlobal - Institut de Salut Global de Barcelona [60793]

Química Inorgànica i Orgànica [994]