dc.contributor.author
Maxwell Villacorta, Lindley Andrés
dc.contributor.author
Martinez, Hector
dc.contributor.author
Martin-Rodriguez, Alejandro
dc.contributor.author
Gómez Coca, Silvia
dc.contributor.author
Rissanen, Kari
dc.contributor.author
Ruiz Sabín, Eliseo
dc.date.issued
2022-04-19T17:27:40Z
dc.date.issued
2022-04-19T17:27:40Z
dc.date.issued
2020-12-23
dc.date.issued
2022-04-19T17:27:40Z
dc.identifier
https://hdl.handle.net/2445/185030
dc.description.abstract
A metalloorganic capsule was synthesized where the ligand is a derivative of heptazine with three carboxylic groups that are coordinated to CuII cations, forming paddle-wheel motifs. Each nanocapsule is neutral, with 12 CuII centers and 8 ligands adopting a rhombicuboctahedron shape. It has almost 3 nm diameter, and the main intermolecular interactions in the solid are π··· π stacking between the C6N7 heptazine moieties. The nanocapsules can form monolayers deposited on graphite as observed by atomic force microscopy, which confirms their stability in solution.
dc.format
application/pdf
dc.publisher
American Chemical Society
dc.relation
Versió postprint del document publicat a: https://doi.org/10.1021/acs.inorgchem.0c03631
dc.relation
Inorganic Chemistry, 2020, vol. 60, num. 2, p. 570-573
dc.relation
https://doi.org/10.1021/acs.inorgchem.0c03631
dc.rights
(c) American Chemical Society , 2020
dc.rights
info:eu-repo/semantics/openAccess
dc.source
Articles publicats en revistes (Química Inorgànica i Orgànica)
dc.title
Metal-Organic Nanocapsules with Functionalized s-Heptazine Ligands
dc.type
info:eu-repo/semantics/article
dc.type
info:eu-repo/semantics/acceptedVersion
