Universitat de Barcelona
2022-04-19T17:27:40Z
2022-04-19T17:27:40Z
2020-12-23
2022-04-19T17:27:40Z
A metalloorganic capsule was synthesized where the ligand is a derivative of heptazine with three carboxylic groups that are coordinated to CuII cations, forming paddle-wheel motifs. Each nanocapsule is neutral, with 12 CuII centers and 8 ligands adopting a rhombicuboctahedron shape. It has almost 3 nm diameter, and the main intermolecular interactions in the solid are π··· π stacking between the C6N7 heptazine moieties. The nanocapsules can form monolayers deposited on graphite as observed by atomic force microscopy, which confirms their stability in solution.
Article
Versió acceptada
Anglès
Lligands; Molècules; Nanociència; Ligands; Molecules; Nanoscience
American Chemical Society
Versió postprint del document publicat a: https://doi.org/10.1021/acs.inorgchem.0c03631
Inorganic Chemistry, 2020, vol. 60, num. 2, p. 570-573
https://doi.org/10.1021/acs.inorgchem.0c03631
(c) American Chemical Society , 2020
