dc.contributor.author
Saladrigas, Mar
dc.contributor.author
Puig Bosch, Jordi
dc.contributor.author
Bonjoch i Sesé, Josep
dc.contributor.author
Bradshaw, Ben
dc.date.issued
2021-01-28T08:58:53Z
dc.date.issued
2021-10-05T05:10:13Z
dc.date.issued
2020-10-05
dc.date.issued
2021-01-28T08:58:54Z
dc.identifier
https://hdl.handle.net/2445/173441
dc.description.abstract
The intermolecular reductive radical coupling of aldehydes with nonactivated alkenes, employing metal hydride atom transfer (MHAT) catalysis with a combination of FeII and FeIII salts, is described. This constitutes the first use of aldehydes as viable acceptor groups in MHAT reactions. The insights gained in this study led to the reexamination of the previously reported intramolecular version of the reaction, and the addition of FeII salts allowed the development of a more efficient second-generation approach.
dc.format
application/pdf
dc.format
application/pdf
dc.publisher
American Chemical Society
dc.relation
Versió postprint del document publicat a: https://doi.org/10.1021/acs.orglett.0c03081
dc.relation
Organic Letters, 2020, vol. 22, p. 8111-8115
dc.relation
https://doi.org/10.1021/acs.orglett.0c03081
dc.rights
(c) American Chemical Society , 2020
dc.rights
info:eu-repo/semantics/openAccess
dc.source
Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica)
dc.subject
Enllaços químics
dc.subject
Química orgànica
dc.subject
Chemical bonds
dc.subject
Organic chemistry
dc.title
Iron-Catalyzed Radical Intermolecular Addition of Unbiased Alkenes to Aldehydes
dc.type
info:eu-repo/semantics/article
dc.type
info:eu-repo/semantics/acceptedVersion
