Stereospecific SN2@P reactions: Novel access to bulky P-stereogenic ligands

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RECERCAT Home > Universitat de Barcelona > Química Inorgànica i Orgànica > Articles publicats en revistes (Química Inorgànica i Orgànica) > View document

To access the full text documents, please follow this link: http://hdl.handle.net/2445/68334

dc.contributor	Universitat de Barcelona
dc.contributor.author	Orgué Gassol, Sílvia
dc.contributor.author	Flores-Gaspar, Areli
dc.contributor.author	Biosca, Maria
dc.contributor.author	Pàmies, Oscar
dc.contributor.author	Diéguez, Montserrat
dc.contributor.author	Riera i Escalé, Antoni
dc.contributor.author	Verdaguer i Espaulella, Xavier
dc.date	2015-12-04T10:43:32Z
dc.date	2015-10-02
dc.date	2015-12-04T10:43:32Z
dc.identifier.citation	1359-7345
dc.identifier.citation	654578
dc.identifier.uri	http://hdl.handle.net/2445/68334
dc.format	4 p.
dc.format	application/pdf
dc.language.iso	eng
dc.publisher	Royal Society of Chemistry
dc.relation	Reproducció del document publicat a: http://dx.doi.org/10.1039/c5cc07504a
dc.relation	Chemical Communications, 2015, vol. 51, p. 17548-17551
dc.relation	http://dx.doi.org/10.1039/c5cc07504a
dc.rights	cc by (c) Orgué Gassol, Sílvia et al., 2015
dc.rights	info:eu-repo/semantics/openAccess
dc.rights	http://creativecommons.org/licenses/by/3.0/es/
dc.subject	Hidròlisi
dc.subject	Lligands
dc.subject	Catàlisi asimètrica
dc.subject	Compostos de bor
dc.subject	Hydrolysis
dc.subject	Ligands
dc.subject	Enantioselective catalysis
dc.subject	Boron compounds
dc.title	Stereospecific SN2@P reactions: Novel access to bulky P-stereogenic ligands
dc.type	info:eu-repo/semantics/article
dc.type	info:eu-repo/semantics/publishedVersion
dc.description.abstract	The stereospecific hydrolysis of bulky aminophosphine boranes is reported for the first time. The resulting phosphinous acid boranes, upon activation, undergo stereospecific nucleophilic substitution reaction at the phosphorous center with amine nucleophiles. The combination of these two processes provides a novel access to bulky P*-ligands.

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