Coordination [CoII2] and [CoIIZnII] helicates showing slow magnetic relaxation

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RECERCAT Home > Universitat de Barcelona > Química Inorgànica i Orgànica > Articles publicats en revistes (Química Inorgànica i Orgànica) > View document

To access the full text documents, please follow this link: http://hdl.handle.net/2445/142544

dc.contributor	Universitat de Barcelona
dc.contributor.author	Diego, Rosa
dc.contributor.author	Pavlov, Alexander
dc.contributor.author	Darawsheh, Mohanad D.
dc.contributor.author	Aleshin, Dimitry
dc.contributor.author	Nehrkorn, Joscha
dc.contributor.author	Nelyubina, Yulia
dc.contributor.author	Roubeau, Olivier
dc.contributor.author	Novikov, Valentin
dc.contributor.author	Aromí Bedmar, Guillem
dc.date	2019-10-17T13:13:28Z
dc.date	2019-07-08
dc.date	2019-10-17T13:13:28Z
dc.date	info:eu-repo/date/embargoEnd/2020-07-08
dc.identifier.citation	0020-1669
dc.identifier.citation	692135
dc.identifier.uri	http://hdl.handle.net/2445/142544
dc.format	5 p.
dc.format	application/pdf
dc.language.iso	eng
dc.publisher	American Chemical Society
dc.relation	Versió postprint del document publicat a: https://doi.org/10.1021/acs.inorgchem.9b01334
dc.relation	Inorganic Chemistry, 2019, vol. 58, num. 15, p. 9562-9566
dc.relation	https://doi.org/10.1021/acs.inorgchem.9b01334
dc.rights	(c) American Chemical Society , 2019
dc.rights	info:eu-repo/semantics/embargoedAccess
dc.subject	Molècules
dc.subject	Propietats magnètiques
dc.subject	Molecules
dc.subject	Magnetic properties
dc.title	Coordination [CoII2] and [CoIIZnII] helicates showing slow magnetic relaxation
dc.type	info:eu-repo/semantics/article
dc.type	info:eu-repo/semantics/acceptedVersion
dc.description.abstract	The slow magnetic relaxation of CoII ions in the elusive intermediate geometry between the trigonal prism and antiprism has been studied on the new [Co2L3]4+ and [CoZnL3]4+ coordination helicates [L is a bis(pyrazolylpyridine) ligand]. Solution paramagnetic 1H NMR and solid-state magnetization measurements unveil single-molecule-magnet behavior with small axial anisotropy, as predicted previously.

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