dc.contributor.author |
Muñiz, Kilian |
dc.contributor.author |
Barreiro, Laura |
dc.contributor.author |
Romero, Martín |
dc.contributor.author |
Martínez, Claudio |
dc.date.accessioned |
2018-06-15T14:06:56Z |
dc.date.available |
2018-06-15T14:06:56Z |
dc.date.issued |
2017-03-09 |
dc.identifier.uri |
http://hdl.handle.net/2072/326411 |
dc.format.extent |
4354 p. |
dc.language.iso |
eng |
dc.publisher |
J. Am. Chem. Soc. |
dc.rights |
L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons: http://creativecommons.org/licenses/by-nc-nd/4.0/ |
dc.source |
RECERCAT (Dipòsit de la Recerca de Catalunya) |
dc.subject.other |
Quimica |
dc.title |
Catalytic Asymmetric Diamination of Styrenes |
dc.type |
info:eu-repo/semantics/article |
dc.type |
info:eu-repo/semantics/draft |
dc.embargo.terms |
cap |
dc.rights.accessLevel |
info:eu-repo/semantics/openAccess |
dc.description.abstract |
An enantioselective catalytic vicinal diamination of styrenes is reported, which proceeds under entirely intermolecular reaction control. It relies on a chirally modified aryliodine(I) catalyst and proceeds within an iodine(I/III) manifold with conventional 3-chloroperbenzoic acid as a terminal oxidant. An environmentally benign solvent combination not only adds to the attractiveness of the process but also slows down the rate of the undesired background reaction. A total of 30 examples are presented, which consistently provide high enantiomeric excesses in the range 91–98%. |