Títol:
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Towards Uniform Iodine-Catalysis: Intramolecular C-H-Amination of Arenes under Visible Light
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Autor/a:
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Martínez, Claudio; Bosnidou, Alexandra E.; Allmendinger, Simon; Muñiz, Kilian
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Abstract:
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A photochemical catalytic amination of arenes is presented. The reaction proceeds under benign iodine catalysis in the presence of visible light as the initiator and provides access to a range of differently substituted arylamines. A total of 29 examples demonstrate the broad applicability of this mild oxidation method. The scope of the reaction could further be expanded to silyl-tethered derivatives, which undergo intramolecular amination upon formation of seven-membered heterocycles. Cleavage of the silicon tether provides access to the corresponding 3-substitued anilines. |
Data de publicació:
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2016 |
Matèries:
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amination arenes catalysis iodine visible light |
Drets:
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Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim |
Tipus de document:
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Article |
DOI:
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https://dx.doi.org/10.1002/chem.201602138
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Publicat per:
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WIley
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Publicat a:
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Chemistry European Journal
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