dc.contributor.author |
Romero, Martín |
dc.contributor.author |
Fra,Laura |
dc.contributor.author |
Lishchynskyi, Anton |
dc.contributor.author |
Martínez, Claudio |
dc.contributor.author |
Streuff, Jan |
dc.contributor.author |
Muñiz, Kilian |
dc.date.accessioned |
2018-01-18T10:11:16Z |
dc.date.accessioned |
2018-02-15T10:28:32Z |
dc.date.available |
2018-01-18T10:11:16Z |
dc.date.available |
2018-02-15T10:28:32Z |
dc.date.issued |
2015 |
dc.identifier.uri |
http://hdl.handle.net/2072/226413 |
dc.identifier.uri |
http://hdl.handle.net/2072/305859 |
dc.language.iso |
eng |
dc.publisher |
Elsevier |
dc.relation |
Ministerio de Economia y Competitivad |
dc.relation |
Explora grants to K. M., and Severo Ochoa Excellence Accreditation 2014-2018 to ICIQ, |
dc.relation |
Photoyodocat (Mineco Explora) |
dc.relation.ispartof |
Tetrahedron |
dc.rights |
2016 Elsevier B.V. |
dc.subject.other |
Amination |
dc.subject.other |
Catalysis |
dc.subject.other |
C-H functionalization |
dc.subject.other |
Iodine |
dc.subject.other |
Oxidation |
dc.title |
Amidato complexes of ruthenium, rhodium and iridium from concise NeH bond activation: exploration in catalysis |
dc.type |
info:eu-repo/semantics/article |
dc.relation.projectID |
CTQ2013-50105-EXP I I SEV-2013-0319 |
dc.identifier.doi |
https://dx.doi.org/10.1016/j.tet.2015.03.028 |
dc.rights.accessLevel |
info:eu-repo/semantics/openAccess |
dc.description.abstract |
Acceptor-substituted N-H groups as found in carbamides and sulfonamides are readily activated through suitable unsaturated metal complexes applying the concept of metal-ligand bifunctionality. This process constitutes the basis for an enantioselective intramolecular addition of N-H groups onto activated alkenes. The resulting compounds can also be employed as catalyst precursors for transferhydrogenation. |