Enantioselective Vicinal Diacetoxylation of Alkenes under Chiral Iodine(III) Catalysis

doi:https://dx.doi.org/10.1055/s-0035-1561313

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RECERCAT Home > Centres de Recerca de Catalunya (CERCA) > Institut Català d'Investigació Química (ICIQ) > Papers > View document

Use this identifier to quote or link this document: http://hdl.handle.net/2072/226412

dc.contributor.author	Wöstea, Thirsten H.
dc.contributor.author	Muñiz, Kilian
dc.date.accessioned	2018-01-18T10:11:15Z
dc.date.accessioned	2018-02-15T10:28:32Z
dc.date.available	2018-01-18T10:11:15Z
dc.date.available	2018-02-15T10:28:32Z
dc.date.issued	2016
dc.identifier.uri	http://hdl.handle.net/2072/226412
dc.identifier.uri	http://hdl.handle.net/2072/305858
dc.language.iso	eng
dc.publisher	Thieme
dc.relation	Ministerio de Economia y Competitivad
dc.relation	the Deutsche Forschungsgemeinschaft
dc.relation	Explora grants to K. M.
dc.relation	Severo Ochoa Excellence Accreditation 2014-2018 to ICIQ
dc.relation	Photoyodocat (Mineco Explora)
dc.relation.ispartof	Synthesis Thieme
dc.rights	Georg Thieme Verlag Stuttgart · New York
dc.subject.other	alkenes
dc.subject.other	chirality
dc.subject.other	diacetoxylation
dc.subject.other	hypervalent iodine
dc.subject.other	oxidation
dc.subject.other	Selectfluor
dc.title	Enantioselective Vicinal Diacetoxylation of Alkenes under Chiral Iodine(III) Catalysis
dc.type	info:eu-repo/semantics/article
dc.relation.projectID	CTQ2013-50105-EXP
dc.relation.projectID	CTQ2011-25027
dc.relation.projectID	SEV-2013-0319
dc.relation.projectID	WO 1924/1-1.
dc.identifier.doi	https://dx.doi.org/10.1055/s-0035-1561313
dc.rights.accessLevel	info:eu-repo/semantics/openAccess
dc.description.abstract	Abstract: A procedure for the intermolecular enantioselective dioxygenation of alkenes under iodine(III) catalysis has been developed. This protocol employs Selectfluor as the terminal oxidant together with a defined C2-symmetric aryl iodide as the organocatalyst. This enantioselective reaction proceeds under mild conditions and converts a series of terminal and internal styrenes into the corresponding vicinal diacetoxylation products with up to 96% ee.

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