Utilizad este identificador para citar o enlazar este documento: http://hdl.handle.net/2072/226409

Water-soluble aryl-extended calix[4]pyrroles with unperturbed aromatic cavities: synthesis and binding studies
Hernandez-Alonso, Daniel; Zankowski, Stanislaw; Adriaenssens, Louis; Ballester, Pau

We report the synthesis of a novel, water-soluble aryl-extended calix[4]pyrrole receptor. The water-solubilising groups are placed at the lower rim of the receptor, leaving the binding pocket unperturbed and open for modification. Binding studies were performed with a series of pyridine N-oxides. These studies revealed the ability of the receptor to bind neutral and charged N-oxides in basified water with stability constants higher than 10(4) M-1.

2014
pyridine n-oxides
molecular recognition
anion
receptors
lectins
calixpyrroles
capsules
solvent
© The Royal Society of Chemistry
Artículo
https://dx.doi.org/10.1039/C4ob02108h
ROYAL SOC CHEMISTRY
Organic & Biomolecular Chemistry
         

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