Ring opening polymerization of macrolactones using amines as initiators

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To access the full text documents, please follow this link: http://hdl.handle.net/2117/91092

dc.contributor	Universitat Politècnica de Catalunya. Departament d'Enginyeria Química
dc.contributor	Universitat Politècnica de Catalunya. POL - Polímers Industrials Avançats i Biopolímers Tecnològics
dc.contributor.author	Tinajero, Ernesto
dc.contributor.author	Lavilla, Cristina
dc.contributor.author	Martínez de Ilarduya Sáez de Asteasu, Domingo Antxon
dc.contributor.author	Muñoz Guerra, Sebastián
dc.date	2016
dc.identifier.citation	Tinajero, E., Lavilla, C., Martinez de Ilarduya, A., Muñoz, S. Ring opening polymerization of macrolactones using amines as initiators. A: Reunión del Grupo Especializado de Polímeros (GEP) de la RSEQ y RSEF. "Avances en materiales poliméricos: XIV Reunión del grupo especializado de polímeros (GEP) de la RSEQ y RSEF [5-8 de septiembre]: libro de resúmenes GEP2016". Burgos: 2016, p. 204-206.
dc.identifier.citation	978-84-16283-26-2
dc.identifier.uri	http://hdl.handle.net/2117/91092
dc.language.iso	eng
dc.relation	http://wwww.ubu.es/servicio-de-publicaciones-e-imagen-institucional
dc.relation	info:eu-repo/grantAgreement/ES/1PE/MAT2012-38044-C03-03
dc.rights	info:eu-repo/semantics/openAccess
dc.rights	http://creativecommons.org/licenses/by-nc-nd/3.0/es/
dc.subject	Àrees temàtiques de la UPC::Enginyeria química
dc.subject	Ring-opening polymerization
dc.subject	Ring opening polymerization
dc.subject	macrolactones
dc.subject	pentadecalactone
dc.subject	amine initiators.
dc.subject	Polimerització
dc.title	Ring opening polymerization of macrolactones using amines as initiators
dc.type	info:eu-repo/semantics/publishedVersion
dc.type	info:eu-repo/semantics/conferenceObject
dc.description.abstract	The ring opening polymerization (ROP) of these macrolactones mediated by alcohols as initiators and organic and metal-based catalysts has been reported before with satisfactory results [4,5]. In the present work, the polymerization of these macrolactones has been studied using amines as initiators. The ROP of both PDL and 6HDL was carried out in bulk at 100 oC using 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) as organocatalyst. Distinct types of amines were tested as initiators for the ROP of these macrolactones. The copolymerization reaction was also studied by ROP of PDL and 6HDL with an oligo-polyethylene glycol bis(3-aminopropyl) terminated and an amino-ended homopolypeptide (poly(¿-benzyl a,Lglutamate) as initiator.

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