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Stereospecific SN2@P reactions: Novel access to bulky P-stereogenic ligands

Author

Orgué Gassol, Sílvia

Flores-Gaspar, Areli

Biosca, Maria

Pàmies, Oscar

Diéguez, Montserrat

Riera i Escalé, Antoni

Verdaguer i Espaulella, Xavier

Publication date

2015-12-04T10:43:32Z

2015-10-02

2015-12-04T10:43:32Z

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Abstract

The stereospecific hydrolysis of bulky aminophosphine boranes is reported for the first time. The resulting phosphinous acid boranes, upon activation, undergo stereospecific nucleophilic substitution reaction at the phosphorous center with amine nucleophiles. The combination of these two processes provides a novel access to bulky P*-ligands.

Document Type

Article

Published version

Language

English

Subjects and keywords

Hidròlisi; Lligands; Catàlisi asimètrica; Compostos de bor; Hydrolysis; Ligands; Enantioselective catalysis; Boron compounds

Publisher

Royal Society of Chemistry

Related items

Reproducció del document publicat a: http://dx.doi.org/10.1039/c5cc07504a

Chemical Communications, 2015, vol. 51, p. 17548-17551

http://dx.doi.org/10.1039/c5cc07504a

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Rights

cc by (c) Orgué Gassol, Sílvia et al., 2015

http://creativecommons.org/licenses/by/3.0/es/

This item appears in the following Collection(s)

Institut de Recerca Biomèdica (IRB Barcelona) [418]

ISGlobal - Institut de Salut Global de Barcelona [61310]

Química Inorgànica i Orgànica [1012]