dc.contributor.author
Eusamio, Javier
dc.contributor.author
Saumell Palacios, Nil
dc.contributor.author
Vidal Ferran, Anton
dc.contributor.author
Grabulosa, Arnald
dc.date.accessioned
2026-02-19T20:10:06Z
dc.date.available
2026-02-19T20:10:06Z
dc.date.issued
2026-02-18T13:59:05Z
dc.date.issued
2026-02-18T13:59:05Z
dc.date.issued
2024-07-18
dc.date.issued
2026-02-18T13:59:05Z
dc.identifier
https://hdl.handle.net/2445/227015
dc.identifier.uri
https://hdl.handle.net/2445/227015
dc.description.abstract
The first example of a P-phosphanylphosphorane, Flu�PCy2−PCy2 (L2; Flu = 9-fluorenyl), has been easily prepared
by P-phosphination of lithiated 9-dicyclohexylphosphinofluorene (FluPCy2, L0) with chlorodicyclohexylphosphane. L2 constitutes a
new type of P(III)−P(V) organophosphorus compound, a σ3
λ3
−σ4
λ5 species that is stable under an inert atmosphere in the solid
state. The reaction of L2 with [Rh(diene)2]BR4 causes metalation of the benzylic carbon (C9) of fluorene, giving κ2
-C,P complexes
in which fluorene is coordinated in the η1 form. A complex with the weakly coordinating BArF anion has been isolated and fully
characterized, including its crystal structure obtained by X-ray diffraction.
dc.format
application/pdf
dc.publisher
American Chemical Society
dc.relation
Versió postprint del document publicat a: https://doi.org/10.1021/acs.inorgchem.4c01934
dc.relation
Inorganic Chemistry, 2024, vol. 63, p. 13820-13824
dc.relation
https://doi.org/10.1021/acs.inorgchem.4c01934
dc.rights
(c) American Chemical Society, 2024
dc.rights
info:eu-repo/semantics/openAccess
dc.title
Rhodium(I) Complexes with a n1- Fluorenyl, <em>P</em>-Phosphanyl-Phosphorane Ligand
dc.type
info:eu-repo/semantics/article
dc.type
info:eu-repo/semantics/acceptedVersion
