The template effect of a SiF62- guest drives the formation of a heteroleptic Fe(II) coordination helicate

Capó Serrano, Núria; Barrios Moreno, Leoní Alejandra; Cardona, Joan; Ribas Ariño, Jordi; Teat, Simon J.; Roubeau, Olivier; Aromí Bedmar, Guillem; Capó Serrano, Núria; Barrios Moreno, Leoní Alejandra; Cardona, Joan; Ribas Ariño, Jordi; Teat, Simon J.; Roubeau, Olivier; Aromí Bedmar, Guillem

The template effect of a SiF62- guest drives the formation of a heteroleptic Fe(II) coordination helicate

Author

Capó Serrano, Núria

Barrios Moreno, Leoní Alejandra

Aromí Bedmar, Guillem

Publication date

2023-06-30T08:17:57Z

2023-09-14T05:10:30Z

2022-09-14

2023-06-30T08:17:57Z

Abstract

The anion SiF62− exerts a strong template effect, driving the exclusive assembly of two different bispyridylpyrazolyl ligands into a triple stranded Fe(II) dinuclear heteroleptic helicate, engendering a new class within the large family of coordination helicates.