Polymorphic chiral squaraine crystallites in textured thin films

dc.contributor.author
Zablocki, Jennifer
dc.contributor.author
Arteaga Barriel, Oriol
dc.contributor.author
Balzer, Frank
dc.contributor.author
Hertel, Dirk
dc.contributor.author
Holstein, Julian J.
dc.contributor.author
Clever, Guido
dc.contributor.author
Anhäuser, Jana
dc.contributor.author
Puttreddy, Rakesh
dc.contributor.author
Rissanen, Kari
dc.contributor.author
Meerholz, Klaus
dc.contributor.author
Lützen, Arne
dc.contributor.author
Schiek, Manuela
dc.date.issued
2021-03-02T11:28:09Z
dc.date.issued
2021-03-02T11:28:09Z
dc.date.issued
2020-03-10
dc.date.issued
2021-03-02T11:28:09Z
dc.identifier
0899-0042
dc.identifier
https://hdl.handle.net/2445/174551
dc.identifier
704110
dc.description.abstract
An enantiomerically pure (R)-2-methylpyrrolidine-based anilino squaraine crystallizes in two chiral polymorphs adopting a monoclinicC2 and an orthorhombic P212121structure, respectively. By various thin-film preparation tech-niques, a control of the polymorph formation is targeted. The local texture ofthe resulting textured thin films is connected to the corresponding opticalproperties. Special attention is paid to an unusual Davydov splitting, the aniso-tropic chiroptical response arising from preferred out-of-plane orientation ofthe crystallites, and the impact of the polymorph specific excitonic coupling.
dc.format
13 p.
dc.format
application/pdf
dc.language
eng
dc.publisher
Wiley
dc.relation
Reproducció del document publicat a: https://doi.org/10.1002/chir.23213
dc.relation
Chirality, 2020, vol. 32, p. 619-631
dc.relation
https://doi.org/10.1002/chir.23213
dc.rights
cc-by (c) Zablocki, Jennifer, et al. 2020
dc.rights
http://creativecommons.org/licenses/by/3.0/es/
dc.rights
info:eu-repo/semantics/openAccess
dc.source
Articles publicats en revistes (Física Aplicada)
dc.subject
Dicroisme circular
dc.subject
Difracció de raigs X
dc.subject
Circular dichroism
dc.subject
X-rays diffraction
dc.title
Polymorphic chiral squaraine crystallites in textured thin films
dc.type
info:eu-repo/semantics/article
dc.type
info:eu-repo/semantics/publishedVersion


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