dc.contributor.author
Esteban Jarne, Jordi
dc.contributor.author
Font Bardia, Ma. Mercedes
dc.contributor.author
Sánchez Costa, José
dc.contributor.author
Teat, Simon J.
dc.contributor.author
Escuer Fité, Albert
dc.date.issued
2020-06-12T07:04:03Z
dc.date.issued
2020-06-12T07:04:03Z
dc.date.issued
2020-06-12T07:04:03Z
dc.identifier
https://hdl.handle.net/2445/165286
dc.description.abstract
In the present work, five new Ni5 clusters employing the versatile 2-pyridylcyanoxime ligand have been synthesized and chemically, structurally, and magnetically characterized. The crystallographic examination of these Ni5 clusters together with those already published in the literature, giving a total number of 14 complexes, exhibiting up to 8 different topologies for which the relationship between topology, reaction conditions and magnetic response has been analyzed. DC magnetic measurements were carried in the 300-2 K range for the new complexes and the analysis of the experimental data revealed an antiferromagnetic response for the oximato mediated interactions with a variety of ground states (S = 0, 1, 3) as function of the cluster topology.
dc.format
application/pdf
dc.publisher
American Chemical Society
dc.relation
Versió postprint del document publicat a: https://doi.org/10.1021/ic500057j
dc.relation
Inorganic Chemistry, 2014, vol. 53, num. 6, p. 3194-3203
dc.relation
https://doi.org/10.1021/ic500057j
dc.rights
(c) American Chemical Society , 2014
dc.rights
info:eu-repo/semantics/openAccess
dc.source
Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)
dc.subject
Propietats magnètiques
dc.subject
Teoria quàntica
dc.subject
Magnetic properties
dc.subject
Quantum theory
dc.title
New topologies in pentanuclear nickel/oximato clusters: structural and magnetic characterization
dc.type
info:eu-repo/semantics/article
dc.type
info:eu-repo/semantics/acceptedVersion
