dc.contributor.author
Fernandez-Valparis, Javier
dc.contributor.author
Romo Fernández, Juan Manuel
dc.contributor.author
Romea, Pedro
dc.contributor.author
Urpí Tubella, Fèlix
dc.contributor.author
Kowalski, Hubert
dc.contributor.author
Font Bardia, Ma. Mercedes
dc.date.accessioned
2024-11-28T15:26:39Z
dc.date.available
2024-11-28T15:26:39Z
dc.date.issued
2020-06-06T08:18:06Z
dc.date.issued
2020-06-06T08:18:06Z
dc.date.issued
2015-07-02
dc.date.issued
2020-06-06T08:18:06Z
dc.identifier
http://hdl.handle.net/2445/164597
dc.identifier.uri
http://hdl.handle.net/2445/164597
dc.description.abstract
The structurally simple (Me3P)2NiCl2 complex catalyzes SN1-type alkylations of chiral N-acyl thiazolidinethiones with diarylmethyl methyl ethers and other stable carbenium cations. The former can contain a variety of functional groups and heteroatoms at the α-position. The resultant adducts are isolated as single diastereomers in high yields and can be converted into enantiomerically pure derivatives in a straightforward manner.
dc.format
application/pdf
dc.publisher
American Chemical Society
dc.relation
Versió postprint del document publicat a: https://doi.org/10.1021/acs.orglett.5b01626
dc.relation
Organic Letters, 2015, vol. 17, num. 14, p. 3540-3543
dc.relation
https://doi.org/10.1021/acs.orglett.5b01626
dc.rights
(c) American Chemical Society , 2015
dc.rights
info:eu-repo/semantics/openAccess
dc.source
Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)
dc.subject
Catàlisi asimètrica
dc.subject
Compostos de níquel
dc.subject
Enantioselective catalysis
dc.subject
Nickel compounds
dc.title
Stereoselective alkylation of (S)-N-acyl-4-isopropyl-1,3-thiazolidine-2-thiones catalyzed by (Me3P)2NiCl2
dc.type
info:eu-repo/semantics/article
dc.type
info:eu-repo/semantics/acceptedVersion
