dc.contributor
Universitat Politècnica de Catalunya. Departament d'Enginyeria Química
dc.contributor
Universitat Politècnica de Catalunya. ENCORE - Energy, Catalysis, Process and Reaction Engineering
dc.contributor.author
Llorca Piqué, Jordi
dc.contributor.author
Garcia Verdugo, Eduardo
dc.date.accessioned
2026-03-25T11:24:04Z
dc.date.available
2026-03-25T11:24:04Z
dc.identifier
Llorca, J.; Garcia-Verdugo, E. Wastewater treatment via H2O2 activation and 4-nitrophenol oxidation with iron-doped nickel-azolate frameworks. «Inorganic chemistry communications», Agost 2024, vol. 166, núm. article 112671, 5 p.
dc.identifier
https://hdl.handle.net/2117/459092
dc.identifier
10.1016/j.inoche.2024.112671
dc.identifier.uri
https://hdl.handle.net/2117/459092
dc.description.abstract
An advanced oxidation heterogeneous process completely degrades 4-nitrophenol in weak acid ambient aqueous conditions using post-synthetically iron-doped nickel azolate frameworks. The framework crystallinity, porosity and reactivity of the redox-active iron (II/III) sites, hydroxyl anions and radicals upon H2O2 pretreatment are discussed based on spectroscopic analysis of the reaction mixture and pretreated MOF.
dc.description.abstract
F. G: C. and N. M. acknowledge the “Ramon y Cajal” contract with code RYC2020-028681-I and RYC2021-033167-I funded MCIN/AEI/10.13039/501100011033 and by “ESF investing in your future”, “European Union NextGenerationEU/PRTR”. This work has been partially supported by the projects PID2021- 124695OB-C22, PID2022-142897OA-I00 funded by MICINN-FEDER-AEI 10.13039/501100011033, MICIU/AEI/10.13039/501100011033 and by FEDER, UE. The work is also partially supported by the projects TED2021-129626B-I00 and TED2021-130288B-I00/ funded by MCIN/AEI/10.13039/501100011033/ and by the European Union Next Generation EU-PRTR. FGC thank Generalitat Valenciana (CISEJI/2023/78). E. L. M. and M. G. A. acknowledge the research program of University of Salamanca (PIC2-2022-08). J.L. is a Serra Húnter Fellow and is grateful to the ICREA Academia program and projects MICINN/FEDER PID2021-124572OB-C31//AEI/10.13039/501100011033/FEDER, UE and 2021 SGR 01061.
dc.description.abstract
6 - Aigua Neta i Sanejament
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13 - Acció per al Clima
dc.description.abstract
Postprint (published version)
dc.format
application/pdf
dc.relation
https://www.sciencedirect.com/science/article/pii/S1387700324006543
dc.rights
http://creativecommons.org/licenses/by-nc/4.0/
dc.rights
Attribution-NonCommercial 4.0 International
dc.title
Wastewater treatment via H2O2 activation and 4-nitrophenol oxidation with iron-doped nickel-azolate frameworks