Polyamorphic transitions in Ce-based metallic glasses by synchrotron radiation

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Universitat Politècnica de Catalunya. Departament de Física
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Universitat Politècnica de Catalunya. GCM - Grup de Caracterització de Materials
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Duarte Correa, María Jazmín
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Bruna Escuer, Pere
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Pineda Soler, Eloi
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Crespo Artiaga, Daniel
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Garbarino, Gaston
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Verbeni, Roberto
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Zhao, Kun
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Wang, Wei Hua
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Romero Castro, Aldo Humberto
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Serrano Gutiérrez, Jorge
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2011-12-01
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Duarte, M. [et al.]. Polyamorphic transitions in Ce-based metallic glasses by synchrotron radiation. "Physical review B: condensed matter and materials physics", 1 Desembre 2011, vol. 84, núm. 22, p. 224116.
dc.identifier
1098-0121
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https://hdl.handle.net/2117/189342
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10.1103/PhysRevB.84.224116
dc.description.abstract
We report here on a polyamorphic-phase transition upon application of pressure on a Ce-based metallic glass, Ce70Al10Ni10Cu10, investigated by x-ray diffraction and inelastic x-ray scattering. This alloy is found to display a strong hysteresis in volume per atom upon application and subsequent release of pressure. The observed structural changes are correlated with changes observed by inelastic x-ray scattering in the elastic constants, acoustic mode frequencies, and sound speed. The results reported here point toward three different amorphous phases for this alloy existing in the 0–25 GPa pressure region: low- and high-density states and an intermediate mixed state that displays a hysteresis behavior. Finally, we discuss the impact of Ce concentration on the polyamorphic transition for a series of Ce-based metallic glass alloys and link it to the phase transformation between ¿ -Ce and a-Ce under pressure.
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Peer Reviewed
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Postprint (published version)
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1 p.
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application/pdf
dc.language
eng
dc.relation
http://prb.aps.org/abstract/PRB/v84/i22/e224116
dc.relation
info:eu-repo/grantAgreement/MICINN//MAT2010-14907/ES/PRODUCCION DE VIDRIOS METALICOS MASIVOS. ESTUDIO DE LA ESTRUCTURA LOCAL Y ESTABILIDAD PARA LA MEJORA DE PROPIEDADES MECANICAS 2/
dc.relation
info:eu-repo/grantAgreement/AGAUR/2009SGR-1225
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info:eu-repo/grantAgreement/AGAUR/2009SGR-1251
dc.rights
http://creativecommons.org/licenses/by-nc-nd/3.0/es/
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Open Access
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Attribution-NonCommercial-NoDerivs 3.0 Spain
dc.subject
Àrees temàtiques de la UPC::Física
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Synchrotron radiation
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Cerium -- Effect of radiation on
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Metallic glasses
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Synchrotrons
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Liquid Phase-transition
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High-pressure
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Density
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Silicon Systems
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Cerium
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Radiació sincrotrònica
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Vidres metàl·lics
dc.title
Polyamorphic transitions in Ce-based metallic glasses by synchrotron radiation
dc.type
Article


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