dc.contributor.author |
Fuertes Espinosa, Carles |
dc.contributor.author |
Gómez Torres, Alejandra |
dc.contributor.author |
Morales Martínez, Roser |
dc.contributor.author |
Rodríguez Fortea, Antonio |
dc.contributor.author |
Garcia Simon, Cristina |
dc.contributor.author |
Gándara, Felipe |
dc.contributor.author |
Imaz, Inhar |
dc.contributor.author |
Juanhuix, Judith |
dc.contributor.author |
Maspoch Comamala, Daniel |
dc.contributor.author |
Poblet Rius, Josep M. |
dc.contributor.author |
Echegoyen, Luis |
dc.contributor.author |
Ribas, Xavi |
dc.date |
2018 |
dc.identifier |
https://ddd.uab.cat/record/206942 |
dc.identifier |
urn:10.1002/anie.201806140 |
dc.identifier |
urn:oai:ddd.uab.cat:206942 |
dc.identifier |
urn:scopus_id:85051848496 |
dc.identifier |
urn:articleid:15213773v57n35p11294 |
dc.identifier |
urn:wos_id:000442340000030 |
dc.identifier |
urn:altmetric_id:44050851 |
dc.identifier |
urn:icn2uab:5610846 |
dc.format |
application/pdf |
dc.language |
eng |
dc.publisher |
|
dc.relation |
Agència de Gestió d'Ajuts Universitaris i de Recerca 2017/SGR-264 |
dc.relation |
Agència de Gestió d'Ajuts Universitaris i de Recerca 2017/SGR-629 |
dc.relation |
Ministerio de Economía y Competitividad CTQ2016-77989-P |
dc.relation |
Ministerio de Economía y Competitividad CTQ2017-87269-P |
dc.relation |
Ministerio de Economía y Competitividad SEV-2013-0295 |
dc.relation |
Angewandte Chemie (International ed. Internet) ; Vol. 57, Issue 35 (August 2018), p. 11294-11299 |
dc.rights |
open access |
dc.rights |
Tots els drets reservats. |
dc.rights |
https://rightsstatements.org/vocab/InC/1.0/ |
dc.subject |
Endohedral metallofullerenes |
dc.subject |
Supramolecular capsules |
dc.subject |
Uranium |
dc.title |
Purification of Uranium-based Endohedral Metallofullerenes (EMFs) by Selective Supramolecular Encapsulation and Release |
dc.type |
Article |
dc.description.abstract |
Supramolecular nanocapsule 1⋅(BArF) is able to sequentially and selectively entrap recently discovered U@C and unprecedented ScCU@C, simply by soaking crystals of 1⋅(BArF) in a toluene solution of arc-produced soot. These species, selectively and stepwise absorbed by 1⋅(BArF), are easily released, obtaining highly pure fractions of U@C and ScCU@C in one step. ScCU@C represents the first example of a mixed metal actinide-based endohedral metallofullerene (EMF). Remarkably, the host-guest studies revealed that 1⋅(BArF) is able to discriminate EMFs with the same carbon cage but with different encapsulated cluster and computational studies provide support for these observations. |