Single-crystal-to-single-crystal postsynthetic modification of a metal-organic framework via ozonolysis

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RECERCAT Home > Universitat Autònoma de Barcelona > Articles escrits per personal UAB o publicats per la universitat > View document

Title:	Single-crystal-to-single-crystal postsynthetic modification of a metal-organic framework via ozonolysis
Author:	Albalad, Jorge; Xu, Heng; Gándara, Felipe; Haouas, Mohamed; Martineau-Corcos, Charlotte; Mas Balleste, Ruben; Barnett, Sarah A.; Juanhuix, Judith; Imaz, Inhar; Maspoch Comamala, Daniel
Abstract:	We describe solid-gas phase, single-crystal-to-single-crystal, postsynthetic modifications of a metal-organic framework (MOF). Using ozone, we quantitatively transformed the olefin groups of a UiO-66-type MOF into 1,2,4-trioxolane rings, which we then selectively converted into either aldehydes or carboxylic acids.
Subject(s):	-Gasphase -Metal organic framework -Ozonolysis -Postsynthetic modification
Rights:	open access Tots els drets reservats. https://rightsstatements.org/vocab/InC/1.0/
Document type:	Article
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Uri:	https://ddd.uab.cat/record/206933

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