dc.contributor.author
Pan, Wenkai
dc.contributor.author
Grigoryeva, Anastasia
dc.contributor.author
Bacchiocchi, Corrado
dc.contributor.author
Ballester, Pablo
dc.contributor.author
Valgimigli, Luca
dc.contributor.author
Petroselli, Manuel
dc.date.accessioned
2026-01-09T13:03:00Z
dc.date.issued
2025-12-12
dc.identifier.uri
https://hdl.handle.net/2072/489063
dc.description.abstract
We report a series of endo-functionalized molecular receptors based on a calix[4]pyrrole scaffold, which exhibit Hydrogen Atom Transfer (HAT) reactivity towards free-radicals (e.g., peroxyl radicals). The chemical structure and shape of the molecular receptors affect the affinity towards free-radicals, while host-guest interactions are used to fine-tune the HAT reactivity, mimicking enzyme modulation in biological systems.
ca
dc.publisher
ACS Publications
ca
dc.rights
Attribution 4.0 International
*
dc.rights.uri
http://creativecommons.org/licenses/by/4.0/
*
dc.source
RECERCAT (Dipòsit de la Recerca de Catalunya)
dc.subject.other
Química
ca
dc.title
Enzyme-like Hydrogen Atom Transfer (HAT) Based Endo-Functionalized Molecular Receptors
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dc.type
info:eu-repo/semantics/article
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dc.description.version
info:eu-repo/semantics/acceptedVersion
ca
dc.embargo.terms
12 mesos
ca
dc.relation.projectID
M.P. thanks Government of Catalunya for a Beatriu de Pinós 2021 grant (2021 BP 00028)
ca
dc.relation.projectID
Gobierno de España MICIU/AEI/10.13039/501100011033, FEDER/UE (PID2023-149233NB-IOO) and MICIU/AEI/10.13039/501100011033 (CEX2024-001469-S)
ca
dc.relation.projectID
CERCA Programme/Generalitat de Catalunya
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dc.relation.projectID
AGAUR (2021 SGR 00851)
ca
dc.relation.projectID
European Union - NextGenerationEU under the National Recovery and Resilience Plan (PNRR) - Mission 4 Education and research - Component 2 From research to business - Investment 1.1 Notice Prin 2022 - DD N. 104 del 2/2/2022, from PRIN20227XZKBY - Superoxide responsive redox-active systems and nano smart materials to target ferroptosis – FEROX - CUP J53D23008550006
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dc.relation.projectID
W.P. acknowledges support from China Scholarship Council (CSC)
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dc.identifier.doi
https://doi.org/10.1021/acs.orglett.5c04339
ca
dc.date.embargoEnd
2026-12-12T01:00:00Z
dc.rights.accessLevel
info:eu-repo/semantics/embargoedAccess
