Desymmetrisation of meso-diones promoted by a highly recyclable polymersupported chiral phosphoric acid catalyst

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dc.contributor.author	Clot-Almenara, Lidia
dc.contributor.author	Rodríguez-Escrich, Carles
dc.contributor.author	Pericàs, Miquel A.
dc.date.accessioned	2020-03-13T12:28:45Z
dc.date.available	2020-03-13T12:28:45Z
dc.date.issued	2018-02-12
dc.identifier.uri	http://hdl.handle.net/2072/373962
dc.format.extent	6910 p.
dc.language.iso	eng
dc.rights	L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons:http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.source	RECERCAT (Dipòsit de la Recerca de Catalunya)
dc.subject.other	54
dc.title	Desymmetrisation of meso-diones promoted by a highly recyclable polymersupported chiral phosphoric acid catalyst
dc.type	info:eu-repo/semantics/article
dc.type	info:eu-repo/semantics/acceptedVersion
dc.embargo.terms	cap
dc.relation.projectID	CTQ2015-69136-R
dc.relation.projectID	Grant 2014SGR827
dc.identifier.doi	10.1039/C7RA13471A
dc.rights.accessLevel	info:eu-repo/semantics/openAccess
dc.description.abstract	A polystyrene-supported BINOL-derived chiral phosphoric acid has been applied to the desymmetrisation of meso-diones to produce enantioenriched cyclohexenones. The catalytic resin has proven highly active and robust, giving rise to Hajos–Parrish or Wieland–Miescher type products in good yields and enantioselectivities, while allowing for extended recycling.

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