Title:
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Desymmetrisation of meso-diones promoted by a highly recyclable polymersupported chiral phosphoric acid catalyst
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Author:
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Clot-Almenara, Lidia; Rodríguez-Escrich, Carles; Pericàs, Miquel A.
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Abstract:
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A polystyrene-supported BINOL-derived chiral phosphoric acid has been applied to the desymmetrisation of meso-diones to produce enantioenriched cyclohexenones. The catalytic resin has proven highly active and robust, giving rise to Hajos–Parrish or Wieland–Miescher type products in good yields and enantioselectivities, while allowing for extended recycling. |
Publication date:
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2018-02-12 |
Subject(s):
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54 |
Rights:
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L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons:http://creativecommons.org/licenses/by-nc-nd/4.0/ |
Pages:
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6910 p. |
Document type:
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Article Article - Accepted version |
DOI:
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10.1039/C7RA13471A
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