Dynamic nuclear polarization using polychlorotriphenylmethyl radicals reveals supramolecular polarization transfer effects

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RECERCAT Home > Universitat de Barcelona > Química Inorgànica i Orgànica > Articles publicats en revistes (Química Inorgànica i Orgànica) > View document

To access the full text documents, please follow this link: http://hdl.handle.net/2445/138557

dc.contributor	Universitat de Barcelona
dc.contributor.author	Gabellieri, Cristina
dc.contributor.author	Mugnaini, Verónica
dc.contributor.author	Paniagua, Juan Carlos
dc.contributor.author	Roques, Nans
dc.contributor.author	Oliveros, Malena
dc.contributor.author	Feliz Rodenas, Miguel
dc.contributor.author	Veciana, Jaume
dc.contributor.author	Pons Vallès, Miquel
dc.date	2019-07-30T06:53:16Z
dc.date	2019-07-30T06:53:16Z
dc.date	2010-04-20
dc.date	2019-07-30T06:53:16Z
dc.identifier.citation	1433-7851
dc.identifier.citation	587081
dc.identifier.uri	http://hdl.handle.net/2445/138557
dc.format	13 p.
dc.format	application/pdf
dc.language.iso	eng
dc.publisher	Wiley-VCH
dc.relation	Versió postprint del document publicat a: https://doi.org/10.1002/anie.201000031
dc.relation	Angewandte Chemie-International Edition, 2010, vol. 49, num. 19, p. 3360-3362
dc.relation	https://doi.org/10.1002/anie.201000031
dc.rights	(c) Wiley-VCH, 2010
dc.rights	info:eu-repo/semantics/openAccess
dc.subject	Espectroscòpia de ressonància magnètica nuclear
dc.subject	Polarització (Física nuclear)
dc.subject	Nuclear magnetic resonance spectroscopy
dc.subject	Polarization (Nuclear physics)
dc.title	Dynamic nuclear polarization using polychlorotriphenylmethyl radicals reveals supramolecular polarization transfer effects
dc.type	info:eu-repo/semantics/article
dc.type	info:eu-repo/semantics/acceptedVersion
dc.description.abstract	Polychlorinated trityl radicals (see structure: C black, Cl green, Na gray, O red) used for dynamic nuclear polarization (DNP) showed a new transfer mechanism involving quadrupolar chlorine nuclei. The observation of positive or negative enhancements, depending on the substrate, highlights the supramolecular character of the initial polarization‐transfer process

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