Título:
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Enantioselective formal synthesis of ent-rhynchophylline and ent-isorhynchophylline
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Autor/a:
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Amat Tusón, Mercedes; Ramos, Carlos; Pérez Bosch, Maria; Molins i Grau, Elies; Florindo, Pedro; Santos, Maria M. M.; Bosch Cartes, Joan
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Otros autores:
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Universitat de Barcelona |
Abstract:
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Starting from (S)-tryptophanol, a formal synthesis of ent-rhyncho-phylline and ent-isorhynchophylline, involving stereoselective cyclocondensation, spirocyclization, and alkylation reactions, and the final adjustment of the oxidation level at the oxindole and piperidine moieties, is reported. |
Materia(s):
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-Alcaloides -Síntesi asimètrica -Estereoquímica -Alkaloids -Asymmetric synthesis -Stereochemistry |
Derechos:
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(c) Amat Tusón, Mercedes et al., 2013
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Tipo de documento:
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Artículo Artículo - Versión aceptada |
Editor:
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Royal Society of Chemistry
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Compartir:
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