dc.contributor.author |
Martín-Illán, Jesús Á. |
dc.contributor.author |
Suárez, José Antonio |
dc.contributor.author |
Gómez-Herrero, Julio |
dc.contributor.author |
Ares, Pablo |
dc.contributor.author |
Gallego-Fuente, Daniel |
dc.contributor.author |
Cheng, Youdong |
dc.contributor.author |
Zhao, Dan |
dc.contributor.author |
Maspoch Comamala, Daniel |
dc.contributor.author |
Zamora, Félix |
dc.date |
2022 |
dc.identifier |
https://ddd.uab.cat/record/258961 |
dc.identifier |
urn:10.1002/advs.202104643 |
dc.identifier |
urn:oai:ddd.uab.cat:258961 |
dc.identifier |
urn:pmcid:PMC8895050 |
dc.identifier |
urn:pmc-uid:8895050 |
dc.identifier |
urn:pmid:35038248 |
dc.identifier |
urn:oai:pubmedcentral.nih.gov:8895050 |
dc.identifier |
urn:articleid:21983844v9n7art. 2104643 |
dc.identifier |
urn:icn2uab:6543378 |
dc.format |
application/pdf |
dc.language |
eng |
dc.publisher |
|
dc.relation |
Agencia Estatal de Investigación PID2019-106268GB-C31 |
dc.relation |
Agencia Estatal de Investigación PID2019-106268GB-C32 |
dc.relation |
Agencia Estatal de Investigación PCI2018-093081 |
dc.relation |
Agencia Estatal de Investigación RTI2018-095622-B-I00 |
dc.relation |
Agència de Gestió d'Ajuts Universitaris i de Recerca 2017/SGR-238 |
dc.relation |
Agencia Estatal de Investigación CEX2018-000805-M |
dc.relation |
Ministerio de Economía y Competitividad SEV-2017-0706 |
dc.relation |
Advanced science ; Vol. 9, Issue 7 (March 2022), art. 2104643 |
dc.rights |
open access |
dc.rights |
Aquest document està subjecte a una llicència d'ús Creative Commons. Es permet la reproducció total o parcial, la distribució, la comunicació pública de l'obra i la creació d'obres derivades, fins i tot amb finalitats comercials, sempre i quan es reconegui l'autoria de l'obra original. |
dc.rights |
https://creativecommons.org/licenses/by/4.0/ |
dc.subject |
Aerogels |
dc.subject |
COF-membranes |
dc.subject |
Covalent organic frameworks |
dc.subject |
Gas mixtures separation |
dc.subject |
Porous materials |
dc.title |
Ultralarge Free-Standing Imine-Based Covalent Organic Framework Membranes Fabricated via Compression |
dc.type |
Article |
dc.description.abstract |
Demand continues for processing methods to shape covalent organic frameworks (COFs) into macroscopic objects that are needed for their practical applications. Herein, a simple compression method to prepare large-scale, free-standing homogeneous and porous imine-based COF-membranes with dimensions in the centimeter range and excellent mechanical properties is reported. This method entails the compression of imine-based COF-aerogels, which undergo a morphological change from an elastic to plastic material. The COF-membranes fabricated upon compression show good performances for the separation of gas mixtures of industrial interest, N2/CO2 and CH4/CO2. It is believed that the new procedure paves the way to a broader range of COF-membranes. |