In the Neolithic Gavà mines, variscite and turquoise were exploited for ornaments manufacturing, although some prospective pits and tunnels were dug on other similar greenish minerals such as smectite or kandite. A 3D study of the distribution of mineral phases allows us to determine the parameters involved in variscite colours. Methods are comprised of quantitative colourimetry, thin section petrography, SEM-BSE-EDS, EMPA, XRD, Raman spectroscopy, and 57Fe Mössbauer spectrometry. Mapping of the mines indicates that colour is not directly dependent on depth. Although variscite from Gavà is poor in Cr3+ and V+3 compared with gemmy variscite from other localities, the deep green samples content has the highest values of Cr3+. In the case of cryptocrystalline mixtures with jarosite, phosphosiderite, or goethite, variscite tends to acquire a greenish brown to olivaceous hue. If white minerals such as quartz, kandite, crandallite, or alunite are involved in the mixtures, variscite and turquoise colours become paler.