Títol:
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Design and Synthesis of a Noninnocent Multitopic Catechol and Pyridine Mixed Ligand : Nanoscale Polymers and Valence Tautomerism
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Autor/a:
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Guardingo Melián, Mireia; Busqué Sánchez, Félix; Novio Vázquez, Fernando; Ruiz-Molina, Daniel
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Abstract:
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The design and synthesis of a new redox-active ligand combining catechol and pyridine units have allowed the achievement of cobalt-based nanoscale coordination polymer particles in a single-step exhibiting a switchable valence tautomeric behavior and thermal hysteresis. The combination of polymerizing capabilities with redox-active responses in a unique ligand leads to the formation of nanoparticles exhibiting a gradual valence tautomeric interconversion in the 35-370 K temperature range. Using one single ligand to obtain these nanoparticles facilitates possible nanostructure formation methodologies. (Chemical Equation Presented). |
Drets:
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open access
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Tipus de document:
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Article |
Publicat per:
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Uri:
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https://ddd.uab.cat/record/212905
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