Assembly of Complex 1,4‐Cycloheptadienes by (4+3) Cycloaddition of Rhodium(II) and Gold(I) Non‐Acceptor Carbenes

doi:10.1002/anie.202012092

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RECERCAT Home > Centres de Recerca de Catalunya (CERCA) > Institut Català d'Investigació Química (ICIQ) > Papers > View document

Use this identifier to quote or link this document: http://hdl.handle.net/2072/449892

dc.contributor.author	Armengol-Relats, Helena
dc.contributor.author	Mato, Mauro
dc.contributor.author	Echavarren, Antonio M.
dc.date.accessioned	2021-05-04T09:44:15Z
dc.date.available	2021-05-04T09:44:15Z
dc.date.issued	2020-10-20
dc.identifier.uri	http://hdl.handle.net/2072/449892
dc.format.extent	1916 p.
dc.language.iso	eng
dc.rights	L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons:http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.source	RECERCAT (Dipòsit de la Recerca de Catalunya)
dc.subject.other	54
dc.title	Assembly of Complex 1,4‐Cycloheptadienes by (4+3) Cycloaddition of Rhodium(II) and Gold(I) Non‐Acceptor Carbenes
dc.type	info:eu-repo/semantics/article
dc.type	info:eu-repo/semantics/acceptedVersion
dc.embargo.terms	cap
dc.relation.projectID	PID2019- 104815GB-I00
dc.relation.projectID	CEX2019-000925-S
dc.relation.projectID	Advanced Grant No. 835080
dc.relation.projectID	2017 SGR 1257
dc.identifier.doi	10.1002/anie.202012092
dc.rights.accessLevel	info:eu-repo/semantics/openAccess
dc.description.abstract	The formal (4+3) cycloaddition of 1,3‐dienes with Rh(II) and Au(I) non‐acceptor vinyl carbenes, generated from vinylcycloheptatrienes or alkoxyenynes, respectively, leads to 1,4‐cycloheptadienes featuring complex and diverse substitution patterns, including natural dyctiopterene C′ and a hydroxylated derivative of carota‐1,4‐diene. A complete mechanistic picture is presented, in which Au(I) and Rh(II) non‐acceptor vinyl carbenes were shown to undergo a vinylcyclopropanation/Cope rearrangement or a direct (4+3) cycloaddition that takes place in a non‐concerted manner.

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