Synthesis of Rumphellaone A and Hushinone by a Gold-Catalyzed [2 + 2] Cycloaddition

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Title:	Synthesis of Rumphellaone A and Hushinone by a Gold-Catalyzed [2 + 2] Cycloaddition
Author:	Ranieri, Beatrice; Obradors, Carla; Mato, Mauro; Echavarren, Antonio M.
Abstract:	The enantioselective total synthesis of rumphellaone A has been accomplished in 12 steps via a diastereoselective gold(I)-catalyzed [2 + 2] macrocyclization of a 1,10-enyne as the key step to build the cyclobutene moiety. This concise approach has also led to the total synthesis of husinone.
Publication date:	2016-05-14
Subject(s):	Quimica
Rights:	L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons: http://creativecommons.org/licenses/by-nc-nd/4.0/
Pages:	1614 p.
Document type:	Article Article - Draft
DOI:	10.1021/acs.orglett.6b00473
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