dc.contributor.author
Liu, Zhong
dc.contributor.author
D'Amico, Francesco
dc.contributor.author
Martin, Ruben
dc.date.accessioned
2024-10-17T13:24:50Z
dc.date.accessioned
2024-12-16T11:52:30Z
dc.date.available
2024-10-17T13:24:50Z
dc.date.available
2024-12-16T11:52:30Z
dc.date.issued
2024-10-10
dc.identifier.uri
http://hdl.handle.net/2072/537874
dc.description.abstract
Herein, we report a regiodivergent 1,n-dicarbofunctionalization of unactivated olefins enabled by a Ni-catalyzed radical relay that forges both C(sp3)-C(sp3) and C(sp2)–C(sp3) linkages, even at long-range. Initial studies support an intertwined scenario resulting from the merger of an atom-transfer radical addition (ATRA) and a chain-walking event, with site-selectivity being dictated by a judicious choice of the ligand backbone.
eng
dc.format.extent
7 p.
cat
dc.publisher
ACS Publications
cat
dc.source
RECERCAT (Dipòsit de la Recerca de Catalunya)
dc.subject.other
Química
cat
dc.title
Regiodivergent Radical-Relay Alkene Dicarbofunctionalization
cat
dc.type
info:eu-repo/semantics/article
cat
dc.type
info:eu-repo/semantics/publishedVersion
cat
dc.subject.udc
54 - Química
cat
dc.relation.projectID
FEDER/MCI PID2021-123801NB-I00, PID 2019-110008GB-I00
cat
dc.relation.projectID
MCI/AIE (Severo Ochoa Excellence Accreditation 2002-2023, CEX2019-000925-S)
cat
dc.relation.projectID
Z. L. thanks the European Union's research and innovation programme Horizon Europe under the Marie Sklodowska-Curie grant agreement 101154335 (FLUORDIOX) for a postdoctoral fellowship
cat
dc.identifier.doi
https://doi.org/10.1021/jacs.4c10204
dc.rights.accessLevel
info:eu-repo/semantics/openAccess
