Controlled Synthesis of Bioderived Poly(limonene carbonate)-Oligolysine Hybrid Macromolecules

dc.contributor.author
Skoulas, Dimitrios
dc.contributor.author
Tolentino, Ainhoa
dc.contributor.author
Kleij, Arjan W.
dc.date.accessioned
2024-10-02T10:43:59Z
dc.date.accessioned
2024-12-16T11:52:26Z
dc.date.available
2024-10-02T10:43:59Z
dc.date.available
2024-12-16T11:52:26Z
dc.date.issued
2024-09-19
dc.identifier.uri
http://hdl.handle.net/2072/537847
dc.description.abstract
A straightforward and stepwise functionalization of poly(limonene carbonate) (PLC) was achieved through the use of thiol–ene click chemistry introducing primary amine groups. These amines are initiating points for N-carboxy anhydride (NCA) ring-opening polymerization (ROP) reactions, allowing us to modify the PLC backbone with oligolysine fragments, thereby creating a polymer brush type macromolecule. These newly prepared biohybrid structures show a clear hydrophilic behavior as evident from their physical behavior and contact angle measurements.
eng
dc.format.extent
6 p.
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dc.language.iso
eng
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dc.publisher
ACS Publications
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dc.rights
CC-BY-NC-ND 4.0
dc.source
RECERCAT (Dipòsit de la Recerca de Catalunya)
dc.subject.other
Química
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dc.title
Controlled Synthesis of Bioderived Poly(limonene carbonate)-Oligolysine Hybrid Macromolecules
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dc.type
info:eu-repo/semantics/article
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dc.type
info:eu-repo/semantics/publishedVersion
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dc.subject.udc
54 - Química
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dc.embargo.terms
cap
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dc.relation.projectID
CERCA Program/Generalitat de Catalunya
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dc.relation.projectID
ICREA
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dc.relation.projectID
MICINN (PID2020-112684GB-100 and Severo Ochoa Excellence Accreditation 2020–2023 CEX2019-000925-S)
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dc.relation.projectID
AGAUR (2021-SGR-00853)
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dc.relation.projectID
European Union’s Horizon 2020 research and innovation program under Marie Skłodowska-Curie grant agreement No. 801342 (Tecniospring INDUSTRY) and the Government of Catalonia’s Agency for Business Competitiveness (ACCIÓ)
cat
dc.identifier.doi
https://doi.org/10.1021/acsmacrolett.4c00461
dc.rights.accessLevel
info:eu-repo/semantics/openAccess


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