dc.contributor.author
Hammarback, L. Anders
dc.contributor.author
Medina-Gil, Tania
dc.contributor.author
Sadurní, Anna
dc.contributor.author
Echavarren, Antonio M.
dc.date.accessioned
2024-07-19T07:16:07Z
dc.date.accessioned
2024-12-16T11:52:09Z
dc.date.available
2024-07-19T07:16:07Z
dc.date.available
2024-12-16T11:52:09Z
dc.date.issued
2024-07-18
dc.identifier.uri
http://hdl.handle.net/2072/537745
dc.description.abstract
Acetylene has been underexploited despite being a highly valuable feedstock for chemical synthesis. We have developed the first true gold(I)-catalyzed intermolecular three-component reaction between acetylene, alkenes, and alcohols to afford β-vinyl hemiaminal scaffolds from N-vinyl amides. Unusual biscyclopropyl and 3-vinyl N-heterocyclic scaffolds were obtained through the incorporation of a second N-vinyl unit or tethered alkene into the starting material.
eng
dc.format.extent
5 p.
cat
dc.publisher
ACS Publications
cat
dc.rights
CC-BY-NC-ND 4.0
dc.source
RECERCAT (Dipòsit de la Recerca de Catalunya)
dc.subject.other
Química
cat
dc.title
Three-Component Gold(I)-Catalyzed Alkoxyvinylation
cat
dc.type
info:eu-repo/semantics/article
cat
dc.type
info:eu-repo/semantics/publishedVersion
cat
dc.subject.udc
54 - Química
cat
dc.relation.projectID
MCIN/AEI/10.13039/501100011033 (PID2019-104815GB-I00 and CEX2019-000925-S)
cat
dc.relation.projectID
European Research Council (Advanced Grant 835080)
cat
dc.relation.projectID
AGAUR (2021 SGR 01256)
cat
dc.relation.projectID
CERCA Program/Generalitat de Catalunya
cat
dc.relation.projectID
L.A.H. thanks the European Union (Horizon 2020 Marie Skłodowska-Curie Postdoctoral Fellowship, H2020-MSCA-IF-2020 under Grant Agreement No. 101029012-GASGOLD)
cat
dc.relation.projectID
T.M.-G. thanks the MCIN/AEI for a FPI predoctoral fellowship (PRE2020-092105)
cat
dc.relation.projectID
A.S. thanks the European Union (H2020 MSCACOFUND 801474 Postdoctoral Fellowship, GA 801474)
cat
dc.identifier.doi
https://doi.org/10.1021/acs.orglett.4c02102
dc.rights.accessLevel
info:eu-repo/semantics/openAccess
