dc.contributor.author
Velasco-Rubio, Álvaro
dc.contributor.author
Velasco-Rubio, Álvaro
dc.contributor.author
Cong, Fei
dc.contributor.author
Tian, Yubiao
dc.contributor.author
Martin, Ruben
dc.date.accessioned
2024-02-06T12:29:23Z
dc.date.accessioned
2024-04-23T10:49:21Z
dc.date.available
2024-12-13T23:45:11Z
dc.date.issued
2023-12-14
dc.identifier.uri
http://hdl.handle.net/2072/537199
dc.description.abstract
A nickel-catalyzed multicomponent reaction that rapidly and reliably accesses [1,3]-bis-organometallic reagents from allenes is reported. The protocol exhibits a predictable regioselectivity pattern that enables the incorporation of B,B(Si) fragments across the allene backbone under mild conditions, thus offering a complementary platform for accessing polyorganometallic reagents possessing both sp2 and sp3 hybridization from readily available precursors.
eng
dc.format.extent
7 p.
cat
dc.publisher
ACS Publications
cat
dc.source
RECERCAT (Dipòsit de la Recerca de Catalunya)
dc.subject.other
Química
cat
dc.title
Ni-Catalyzed 1,2-Alkyl Borylation and Silylation of Allenes En Route to [1,3]-Bis-Organometallic Reagents
cat
dc.type
info:eu-repo/semantics/article
cat
dc.type
info:eu-repo/semantics/acceptedVersion
cat
dc.relation.projectID
MICIU (PID2021-123801NB-I00)
cat
dc.relation.projectID
MCI/AIE (Severo Ochoa Excellence Accreditation 2020-2023, CEX2019-000925-S)
cat
dc.relation.projectID
A.V.-R. thanks MICINN, AEI and European Union «NextGenerationEU»/PRTR» for a postdoctoral fellowship
cat
dc.relation.projectID
F.C. and Y.T. thank China Scholarship Council (CSC) for predoctoral fellowships
cat
dc.identifier.doi
https://doi.org/10.1021/acs.orglett.3c03574
dc.rights.accessLevel
info:eu-repo/semantics/openAccess
