dc.contributor.author
Tobajas-Curiel, Gloria
dc.contributor.author
Sun, Qingqing
dc.contributor.author
Sanders, Jeremy K. M.
dc.contributor.author
Ballester, Pablo
dc.contributor.author
Hunter, Christopher A.
dc.date.accessioned
2023-12-12T13:56:25Z
dc.date.accessioned
2024-04-23T10:44:04Z
dc.date.available
2023-12-12T13:56:25Z
dc.date.available
2024-04-23T10:44:04Z
dc.date.issued
2023-11-13
dc.identifier.uri
http://hdl.handle.net/2072/537117
dc.description.abstract
Chemical double mutant cycles were used to measure the interaction of a N-methyl pyridinium cation with a π-box in a calix[4]pyrrole receptor. Although the cation–π interaction is attractive (−11 kJ mol−1), it is 7 kJ mol−1 less favourable than the corresponding aromatic interaction with the isosteric but uncharged tolyl group.
eng
dc.format.extent
3 p.
cat
dc.publisher
Royal Society of Chemistry
cat
dc.rights
CC-BY. Creative Commons Attribution 3.0
dc.source
RECERCAT (Dipòsit de la Recerca de Catalunya)
dc.subject.other
Química
cat
dc.title
Solvation rules: aromatic interactions outcompete cation-π interactions in synthetic host-guest complexes in water
cat
dc.type
info:eu-repo/semantics/article
cat
dc.type
info:eu-repo/semantics/publishedVersion
cat
dc.relation.projectID
Herchel Smith fund
cat
dc.relation.projectID
Gobierno de España MICINN/AEI/FEDER (PID2020-114020GB-I00 and CEX2019-000925-S)
cat
dc.relation.projectID
CERCA Programme/Generalitat de Catalunya
cat
dc.relation.projectID
AGAUR (2017 SGR 1123)
cat
dc.identifier.doi
https://doi.org/10.1039/D3CC04399A
dc.rights.accessLevel
info:eu-repo/semantics/openAccess
