dc.contributor.author
Pizarro, Juan Diego
dc.contributor.author
Moran-Gonzalez, Lucia
dc.contributor.author
Gonzalez-Fernandez, Ivan
dc.contributor.author
Maseras, Feliu
dc.contributor.author
Fructos, Manuel R
dc.contributor.author
Perez, Pedro J.
dc.date.accessioned
2023-10-09T08:21:48Z
dc.date.accessioned
2024-04-23T10:15:41Z
dc.date.available
2023-10-09T08:21:48Z
dc.date.available
2024-04-23T10:15:41Z
dc.date.issued
2023-07-02
dc.identifier.uri
http://hdl.handle.net/2072/536957
dc.description.abstract
Copper catalysts containing alkoxydiaminophosphine (ADAP) ligand catalyze the selective C3−H functionalization of unprotected indoles upon carbene transfer from donor-acceptor diazo compounds, the N−H bond remaining unaltered during the transformation. Mechanistic studies, including DFT calculations, allows proposing the existence of two competitive pathways, none of them occurring through the formation of cyclopropane intermediates, at variance with previously reported systems.
eng
dc.format.extent
9 p.
cat
dc.publisher
Wiley-VCH
cat
dc.rights
Creative Commons. CC BY 4.0 DEED Attribution 4.0 International
dc.source
RECERCAT (Dipòsit de la Recerca de Catalunya)
dc.subject.other
Química
cat
dc.title
Selective C-H Bond Functionalization of Unprotected Indoles by Donor-Acceptor Carbene Insertion
cat
dc.type
info:eu-repo/semantics/article
cat
dc.type
info:eu-repo/semantics/publishedVersion
cat
dc.relation.projectID
Ministerio de Ciencia e Innovación for Grants PID2020-113797RB-C21, PID2020-112825RB-I00 and CEX2019-000925-S
cat
dc.relation.projectID
Junta de Andalucía (P18-1536)
cat
dc.relation.projectID
Universidad de Huelva (P. O.Feder UHU-202024)
cat
dc.relation.projectID
I.-G. F thanks the Investigo Program for a contract.
cat
dc.relation.projectID
L. M.-G. thanks Generalitat de Catalunya for an FI-Agaur predoctoral contract, 2022FI−B2000621.
cat
dc.identifier.doi
https://doi.org/10.1002/adsc.202300252
dc.rights.accessLevel
info:eu-repo/semantics/openAccess
