dc.contributor.author
García-Padilla, Eduardo
dc.contributor.author
Maseras, Feliu
dc.contributor.author
Echavarren, Antonio M.
dc.date.accessioned
2023-08-31T09:13:17Z
dc.date.accessioned
2024-04-23T10:15:30Z
dc.date.available
2023-08-31T09:13:17Z
dc.date.available
2024-04-23T10:15:30Z
dc.date.issued
2023-08-20
dc.identifier.uri
http://hdl.handle.net/2072/536874
dc.description.abstract
We identify the factors that rule the selectivity in single-cleavage skeletal rearrangements promoted by gold(I) catalysts. We find that stereoconvergence is enabled by a rotational equilibrium when electron-rich substituents are used. The anomalous Z-selective skeletal rearrangement is found to be due to electronic factors, whereas endo-selectivity depends on both steric and electronic factors.
eng
dc.format.extent
9 p.
cat
dc.publisher
ACS Publications
cat
dc.rights
Creative Commons. CC-BY-NC-ND 4.0.
dc.source
RECERCAT (Dipòsit de la Recerca de Catalunya)
dc.subject.other
Química
cat
dc.title
Gold(I)-Catalyzed1,6-Enyne Single-Cleavage Rearrangements:The Complete Picture
cat
dc.type
info:eu-repo/semantics/article
cat
dc.type
info:eu-repo/semantics/publishedVersion
cat
dc.relation.projectID
MCIN/AEI/10.13039/501100011033 (PID2019-104815GB-I00, PID2020-112825RB-I00, and CEX2019-000925-S)
cat
dc.relation.projectID
European Research Council (Advanced Grant 835080)
cat
dc.relation.projectID
AGAUR (2021 SGR 01256 and predoctoral fellowship to EG-P (2020FI_B 00403))
cat
dc.relation.projectID
CERCA Program/Generalitat de Catalunya
cat
dc.identifier.doi
https://doi.org/10.1021/acsorginorgau.3c00028
dc.rights.accessLevel
info:eu-repo/semantics/openAccess
