dc.contributor.author
Xin-Yang, Lv
dc.contributor.author
Roman, Abrams
dc.contributor.author
Martin, Ruben
dc.date.accessioned
2023-06-29T09:08:58Z
dc.date.accessioned
2024-04-23T10:15:19Z
dc.date.available
2023-06-29T09:08:58Z
dc.date.available
2024-04-23T10:15:19Z
dc.date.issued
2022-12-28
dc.identifier.uri
http://hdl.handle.net/2072/535770
dc.description.abstract
Herein, we describe the development of a copper-catalyzed C(sp3)-amination of proaromatic dihydroquinazolinones derived from ketones. The reaction is enabled by the intermediacy of open-shell species arising from homolytic C−C bond-cleavage driven by aromatization. The protocol is characterized by its operational simplicity and generality, including chemical diversification of advanced intermediates.
eng
dc.format.extent
6 p.
cat
dc.publisher
Wiley-VCH
cat
dc.rights
Creative Commons. Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)
dc.source
RECERCAT (Dipòsit de la Recerca de Catalunya)
dc.subject.other
Quimica
cat
dc.title
Copper-Catalyzed C(sp3)-Amination of Ketone-Derived Dihydroquinazolinones by Aromatization-Driven C−C Bond Scission
cat
dc.type
info:eu-repo/semantics/article
cat
dc.type
info:eu-repo/semantics/publishedVersion
cat
dc.relation.projectID
FEDER/MCI PID2021-123801NB-I00
cat
dc.relation.projectID
China Scholarship Council (CSC)
cat
dc.relation.projectID
European Research Council (ERC) under European Union's Horizon 2020 research and innovation program (grant agreement No 883756)
cat
dc.identifier.doi
https://doi.org/10.1002/anie.202217386
dc.rights.accessLevel
info:eu-repo/semantics/openAccess
