dc.contributor.author
Du, Wei
dc.contributor.author
Gadekar, Santosh C.
dc.contributor.author
Velasco-Rubio, Álvaro
dc.contributor.author
Rodrigalvarez, Jesus
dc.contributor.author
Martin, Ruben
dc.date.accessioned
2025-10-07T11:58:32Z
dc.date.available
2025-10-07T11:58:32Z
dc.date.issued
2025-10-06
dc.identifier.uri
http://hdl.handle.net/2072/487540
dc.description.abstract
Herein, we describe a regiodivergent deuteration of pyridotriazoles under mild conditions. Site-selective deuteration can be tuned, controlled, and switched by a subtle interplay of the base and solvent utilized. Given the ease at which pyridotriazoles can be converted into a variety of pyridine congeners, this protocol might offer a new gateway to access a variety of deuterium-labeled pyridine-containing heterocycles in a site-selective, yet predictable, manner.
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dc.publisher
ACS Publications
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dc.rights
Attribution 4.0 International
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dc.rights.uri
http://creativecommons.org/licenses/by/4.0/
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dc.source
RECERCAT (Dipòsit de la Recerca de Catalunya)
dc.subject.other
Química
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dc.title
Regiodivergent Deuteration of Pyridine-Based Heterocycles
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dc.type
info:eu-repo/semantics/article
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dc.description.version
info:eu-repo/semantics/publishedVersion
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dc.relation.projectID
FEDER/MCI PID2021-123801NB-I00, PID2019-110008GB-I00, PID2024-160739NB-I00/MICIU AIE/10.13039/501100011033/FEDER, UE and MCI/AIE (Severo Ochoa Excellence Accreditation 2002-2023, CEX2019-000925-S)
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dc.relation.projectID
W.D. thanks China Scholarship Council (CSC) for a predoctoral fellowship.
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dc.relation.projectID
S.C.G. thanks the European Union’s Harizone 2020 and innovation program under the Marie Skłodowska-Curie grand agreement (894998)
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dc.identifier.doi
https://doi.org/10.1021/acs.orglett.5c02961
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dc.rights.accessLevel
info:eu-repo/semantics/openAccess
