dc.contributor.author
Wang, Hao
dc.contributor.author
Zhang, Huihui
dc.contributor.author
Martínez-Belmonte, Marta
dc.contributor.author
Martin, Ruben
dc.date.accessioned
2025-10-02T07:04:29Z
dc.date.available
2025-10-02T07:04:29Z
dc.date.issued
2025-07-30
dc.identifier.uri
http://hdl.handle.net/2072/487028
dc.description.abstract
Herein, we describe a regiodivergent interrupted chain-walking of unsaturated aliphatic alcohols. The method leverages the potential of traceless groups to forge C(sp3)–C(sp3) and C(sp3)–nitrogen bonds at distal methylene sp3 C–H sites, with site selectivity dictated by a judicious choice of the ligand. The protocol is distinguished by its broad applicability, offering unconventional disconnections to access β/γ-substituted aliphatic alcohols that are difficult to reach otherwise.
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dc.publisher
ACS Publications
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dc.rights
Attribution 4.0 International
*
dc.rights.uri
http://creativecommons.org/licenses/by/4.0/
*
dc.source
RECERCAT (Dipòsit de la Recerca de Catalunya)
dc.subject.other
Química
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dc.title
Regiodivergent Interrupted Ni-Catalyzed Chain-Walking of Unsaturated Alcohol Side-Chains via Traceless Activating Groups
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dc.type
info:eu-repo/semantics/article
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dc.description.version
info:eu-repo/semantics/publishedVersion
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dc.relation.projectID
FEDER/MCI PID2021-123801NB-I00
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dc.relation.projectID
Agencia de Gestió d’Ajuts Universitaris i de Recerca (2021 SGR 001258)
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dc.relation.projectID
MCI/AIE (Severo Ochoa Excellence Accreditation 2002-2023 CEX2019-000925-S)
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dc.relation.projectID
H.W. and H.Z. thank the China Scholarship Council (CSC) for predoctoral fellowships
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dc.identifier.doi
https://doi.org/10.1021/jacs.5c09426
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dc.rights.accessLevel
info:eu-repo/semantics/openAccess
