Pd-Catalyzed Photoinduced Interceptive Decarboxylative Allylation

dc.contributor.author
Haut, Franz-Lucas
dc.contributor.author
Meger, Filip S.
dc.contributor.author
Santiago, Tomás G.
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Fraňová, Paula
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Kocsi, Daniel
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Estornell, Joan V.
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Martínez-Belmonte, Marta
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Benet-Buchholz, Jordi
dc.contributor.author
Martin, Ruben
dc.date.accessioned
2025-05-15T07:24:59Z
dc.date.available
2025-05-15T07:24:59Z
dc.date.issued
2025-05-12
dc.identifier.uri
http://hdl.handle.net/2072/484351
dc.description.abstract
Herein, we describe a photoinduced Pd-catalyzed interceptive decarboxylative allylation of allyl esters. Our protocol provides a new gateway to enable atom pair swaps or a series of contractions and elongations, thus offering unconventional disconnections and a modular yet broadly applicable tool for rapidly and reliably accessing sp3 architectures in drug discovery.
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dc.format.extent
7 p.
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dc.language.iso
eng
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dc.publisher
ACS Publications
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dc.rights
Attribution-NonCommercial-NoDerivatives 4.0 International
*
dc.rights.uri
http://creativecommons.org/licenses/by-nc-nd/4.0/
*
dc.source
RECERCAT (Dipòsit de la Recerca de Catalunya)
dc.subject.other
Química
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dc.title
Pd-Catalyzed Photoinduced Interceptive Decarboxylative Allylation
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dc.type
info:eu-repo/semantics/article
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dc.subject.udc
54
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dc.description.version
info:eu-repo/semantics/publishedVersion
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dc.embargo.terms
cap
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dc.relation.projectID
FEDER/MCI PID2021-123801NB-I00, PID 2019-110008GB-I00
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dc.relation.projectID
MCI/AIE (Severo Ochoa Excellence Accreditation 2002–2023, CEX2019-000925-S)
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dc.relation.projectID
European Union’s Horizon 2020 research and innovation program (grant agreement 883756)
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dc.relation.projectID
F.-L.H. thanks the Alexander von Humboldt Foundation for a Feodor Lynen Research Fellowship. P.F.
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dc.relation.projectID
F.S.M., and J.V.E. thank the Slovak Academic Information Agency (SAIA) for a research mobility grant and for predoctoral fellowships (PRE2022-101700 and FPU22/02453)
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dc.identifier.doi
https://pubs.acs.org/doi/full/10.1021/jacs.5c03044
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dc.rights.accessLevel
info:eu-repo/semantics/openAccess


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