Título:
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Spectroscopic Characterization and Reactivity of Triplet and Quintet Iron(IV) Oxo Complexes in the Gas Phase
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Autor/a:
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Andris, Erik; Jašík, Juraj; Gómez Martín, Laura; Costas Salgueiro, Miquel; Roithová, Jana
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Otros autores:
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Ministerio de Economía y Competitividad (Espanya) |
Abstract:
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El mateix article està publicat a l'edició alemanya de la revista 'Angewandte chemie' (issn 0044-8249, eissn 1521-3757), 2016, vol. 128, núm.11, p. 3701–3705. DOI http://dx.doi.org/10.1002/ange.201511374 |
Abstract:
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Closely structurally related triplet and quintet iron(IV) oxo complexes with a tetradentate aminopyridine ligand were generated in the gas phase, spectroscopically characterized, and their reactivities in hydrogen-transfer and oxygen-transfer reactions were compared. The spin states were unambiguously assigned based on helium tagging infrared photodissociation (IRPD) spectra of the mass-selected iron complexes. It is shown that the stretching vibrations of the nitrate counterion can be used as a spectral marker of the central iron spin state |
Abstract:
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This research was supported by the European Research Council (StG ISORI and BIDECASEOX), the Grant agency
of the Czech Republic (14-20077S), the Spanish MINECO (CTQ2012-37420-C02-01/BQU), and an ICREA Academia
Award to M.C. Computational resources were provided by the MetaCentrum under the program LM2010005 and the
CERIT-SC under the program Centre CERIT Scientific Cloud, part of the Operational Program Research and Development for Innovations, Reg. no. CZ.1.05/3.2.00/08.0144 |
Materia(s):
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-Catalitzadors -Catalysts -Espectroscòpia infraroja -Infrared spectroscopy -Ferro -- Compostos -- Oxidació -Iron compounds -- Oxidation -Espectrometria de masses -Mass spectrometry |
Derechos:
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Attribution-NonCommercial 3.0 Spain
http://creativecommons.org/licenses/by-nc/3.0/es/ |
Tipo de documento:
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Artículo Artículo - Versión publicada |
Editor:
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Wiley-VCH Verlag
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