Enantioselective Total Synthesis of (−)-Nardoaristolone B via a Gold(I)-Catalyzed Oxidative Cyclization

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Title:	Enantioselective Total Synthesis of (−)-Nardoaristolone B via a Gold(I)-Catalyzed Oxidative Cyclization
Author:	Homs, Anna; Muratore, Michael E; Echavarren, Antonio M
Abstract:	The first enantioselective total synthesis of (−)-nardoaristolone B is accomplished by the implementation of an enantio- and diastereoselective copper(I)-catalyzed conjugate addition/enolate trapping sequence and a gold(I)-catalyzed oxidative cyclization (intermolecular oxidant), employed for the first time in total synthesis.
Publication date:	2015-01-07
Subject (UDC):	54 - Química 547 - Química orgánica
Subject(s):	54 - Química
Rights:	L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons: http://creativecommons.org/licenses/by-nc-nd/4.0/
Pages:	3 p.
Document type:	Article Article - Published version
DOI:	10.1021/ol503531n
Published by:	American Chemical Society
Publish at:	Organic Letters
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