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oai:recercat.cat:2445/683342025-12-04T19:32:50Zcom_2072_1057col_2072_478908col_2072_478917col_2072_478933

Stereospecific SN2@P reactions: Novel access to bulky P-stereogenic ligands Orgué Gassol, Sílvia Flores-Gaspar, Areli Biosca, Maria Pàmies, Oscar Diéguez, Montserrat Riera i Escalé, Antoni Verdaguer i Espaulella, Xavier Hidròlisi Lligands Catàlisi asimètrica Compostos de bor Hydrolysis Ligands Enantioselective catalysis Boron compounds The stereospecific hydrolysis of bulky aminophosphine boranes is reported for the first time. The resulting phosphinous acid boranes, upon activation, undergo stereospecific nucleophilic substitution reaction at the phosphorous center with amine nucleophiles. The combination of these two processes provides a novel access to bulky P*-ligands. 2015-12-04T10:43:32Z 2015-10-02 2015-12-04T10:43:32Z info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion 1359-7345 https://hdl.handle.net/2445/68334 654578 26477668 eng Reproducció del document publicat a: http://dx.doi.org/10.1039/c5cc07504a Chemical Communications, 2015, vol. 51, p. 17548-17551 http://dx.doi.org/10.1039/c5cc07504a cc by (c) Orgué Gassol, Sílvia et al., 2015 http://creativecommons.org/licenses/by/3.0/es/ info:eu-repo/semantics/openAccess 4 p. application/pdf Royal Society of Chemistry Articles publicats en revistes (Química Inorgànica i Orgànica)